✦ LIBER ✦

Pyrolysis jet spectroscopy of dichlorosilylene

✍ Scribed by J. Karolczak; Dennis J. Clouthier

Publisher: Elsevier Science
Year: 1993
Tongue: English
Weight: 514 KB
Volume: 201
Category: Article
ISSN: 0009-2614
DOI: 10.1016/0009-2614(93)85093-4

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✦ Synopsis

The laser-induced fluorescence spectrum of SK& in the near-ultraviolet has been recorded using the pyrolysis jet technique. Pyrolysis of SiHCls has been shown to be an effective method of producing SiCla for spectroscopic studies. The spectra show resolved rotational subband structure and chlorine isotope effects. The fundamental vibrational frequencies are v; = 521.6 cm-', ~;=200.6 cm-', u', ~428.9 cm-' and u;= 149.8 cm-', and the band origin is at 30013.5 cm-'. By comparison with the analogous spectra of CCll and GeCla, the band system is assigned to the A 'Br-2 'A, electronic transition.

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