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Pyrolyses of o-alkoxy- and o-alkylthio-N-allylanilines and of some related O-and S-allyl compounds

✍ Scribed by Cadogan, J. I. G.; Hickson, Clare L.; McNab, Hamish


Book ID
126531520
Publisher
Royal Society of Chemistry
Year
1985
Weight
646 KB
Category
Article
ISSN
1472-7781

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Ring-Closing Metathesis of Allylic O,O-
✍ Sapeβ€…S. Kinderman; Robin Doodeman; Jetzeβ€…W. vanβ€…Beijma; Jaapβ€…C. Russcher; Kimβ€…C. πŸ“‚ Article πŸ“… 2002 πŸ› John Wiley and Sons 🌐 English βš– 189 KB πŸ‘ 1 views

A variety of allylic O,O-and N,O-acetals were synthesized using a mild palladium-catalyzed coupling of an alcohol or sulfonamide with an alkyl or aryl 1,2-propadienyl ether. The resulting linear acetals were used for the synthesis of unsaturated rings via ring-closing metathesis, in which the acetal