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Pyrimidines. 75. Syntheses based on acetylpyrimidines. 4,6-Dihydroxy-5-acetylpyrimidine and preparation of 4′,5-bipyrimidines and their derivatives

✍ Scribed by M. A. Mikhaleva; M. N. Repkova; V. P. Mamaev


Book ID
112349224
Publisher
Springer US
Year
1985
Tongue
English
Weight
678 KB
Volume
21
Category
Article
ISSN
0009-3122

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Stereoselective Preparation of 4,5-Dihydroxy-5,6-dihydro-4H-1,2oxazines and Their Derivatives. -cis-Dihydroxylation of the oxazines (I) yields, with exception of (IId), diastereomerically pure 4,5-dihydroxylated 1,2-oxazines which can be converted to a number of derivatives by standard methods.