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Pyridazine derivatives and related compounds, part 8: Synthesis of different heterocycles from 3-hydrazinopyridazine

✍ Scribed by Ali Deeb; Mekky Hassaneen; Mahmoud Kotb

Publisher
John Wiley and Sons
Year
2005
Tongue
English
Weight
99 KB
Volume
16
Category
Article
ISSN
1042-7163

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✦ Synopsis

The reaction of 3-hydrazino-4,5,6-triphenylpyridazine 1 with phenylisothiocyanate in ethanol gave thiocarbamoylhydrazine 2 while in butanol gave triazolo [4,3-b]pyridazinethione 3. Reaction of 1 with ethyl chloroformate gave ethoxycarbamoylhydrazinopyridazine 5 which upon heating it furnished triazolopyridazine 6. Also, the reaction of 1 with chloroacetylchloride gave triazolopyridazine 7. Reaction of 1 with a number of aromatic aldehydes, D-glucose, and pyruvic acid gave the corresponding hydrazones 9,11. Oxidative cyclization of 9a,b gave triazolo [4,3-b]pyridazine 10a,b. On the other hand, reactions of 1 with diethyl oxalate, ethyl acetoacetate, acetylacetone, ethyl cyanoacetate, diacetyl, and with phthalic anhydride are also reported.

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