Pyrene fluorescence quenching by aromatic azides
β Scribed by S. V. Kamyshan; S. V. Litvinchuk; V. V. Korolev; S. I. Eremenko; Yu. P. Tsentalovich; N. P. Gritsan
- Book ID
- 110170696
- Publisher
- Springer
- Year
- 2006
- Tongue
- English
- Weight
- 205 KB
- Volume
- 47
- Category
- Article
- ISSN
- 0023-1584
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Fluorescence quenching of nine aromtic hydrocarbons by cesium chloride in methmolic solution has been meassured t~Sing'pulse fluo&netrY. A log-log relationship between kq, the rate corstant for quenching by CsCI, and kS+T, the inter- system crossing rate of the fluor, appears to,be applicable to the
Ruorescence quenching of aromatic molecules by inorganic anions in H20-EtOH mixtures at 300 K has been studied quantitatively. A linear relationship between log k. (kq is the quenching rate constant) and AC (the free energy change in electron transfer) is obtained indicating that the &on-mduced quen