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Pyrazolylcyclohexanol Complexes of Vanadium − A Temperature- and Solvent-Dependent Monomer−Dimer Equilibrium

✍ Scribed by Holger Glas; Klaus Köhler; Eberhardt Herdtweck; Peter Maas; Michael Spiegler; Werner R. Thiel


Publisher
John Wiley and Sons
Year
2001
Tongue
English
Weight
355 KB
Volume
2001
Category
Article
ISSN
1434-1948

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✍ J. J. Harrison; C. Y. Chan; A. Onopchenko; A. R. Pradhan; M. Petersen 📂 Article 📅 2008 🏛 John Wiley and Sons 🌐 English ⚖ 503 KB

## Abstract A full line‐shape analysis of the VT ^31^P NMR spectra was carried out for the monomer–dimer equilibrium of neutral ZDDP. The energy surface and the energetics of the monomer‐dimer equilibrium (Δ__H__° , Δ__G__° , __E__~a~, Δ__H__^≠^, and Δ__G__^≠^) are reported for three variants where