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(Pyrazolylborato)zinc−Aldehyde Complexes

✍ Scribed by Rainer Walz; Michael Ruf; Heinrich Vahrenkamp

Publisher
John Wiley and Sons
Year
2001
Tongue
English
Weight
274 KB
Volume
2001
Category
Article
ISSN
1434-1948

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✦ Synopsis

The zinc hydroxide complex Tp Cum,Me Zn-OH [1, Tp Cum,Me = tris(3-cumenyl-5-methylpyrazolyl)borate] reacts with trichloroacetaldehyde and pentafluorobenzaldehyde to form the complexes Tp Cum,Me Zn-O(CHOH)R, containing the aldehyde ligands as the deprotonated aldehyde hydrates. 1 and 2-formylphenol, 2,6-diformylphenol and 2-formylthiophenol undergo condensation with the formation of the correspond-

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