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Pyrazolate-bridged binuclear copper(II) complex with diethylenetriamine

✍ Scribed by W. Mori; T. Sakurai; A. Nakahara; Y. Nakao

Publisher
Elsevier Science
Year
1982
Tongue
English
Weight
155 KB
Volume
65
Category
Article
ISSN
0020-1693

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## Abstract A new binucleating bis(terdentate) ligand, 3,5‐[3‐bis(2‐pyridyl)pyrazole‐1‐ylmethyl]pyrazole (HL^2^), was synthesized. Reaction of the deprotonated ligand L^2^ with hydrated Cu^II^ salts gives (μ‐pyrazolato)(μ‐hydroxido)‐bridged binuclear and tetranuclear complexes [L^2^Cu~2~(μ‐OH)(ClO~