𝔖 Bobbio Scriptorium
✦   LIBER   ✦

Pyramidal distortions in the ethylene triplet π,π* state

✍ Scribed by N. Colin Baired; Jerrald R. Swenson


Publisher
Elsevier Science
Year
1973
Tongue
English
Weight
239 KB
Volume
22
Category
Article
ISSN
0009-2614

No coin nor oath required. For personal study only.


📜 SIMILAR VOLUMES


The π,π* assignment of the lowest triple
✍ Y. Tanimoto; H. Kobayashi; S. Nagakura; T. Azumi 📂 Article 📅 1972 🏛 Elsevier Science 🌐 English ⚖ 339 KB

With the aid of the crystullographic data, obtained anew, the Zeeman splitting pattern observed with the longest wavelength singlet-to-triplet absorp!ion of the acetophenone single crystal has been analyzed. The optically active spin state is T,,, which is mixed by spin-orbit interaction with u,rr\*

The theoretical description of the (ππ*)
✍ T.H. Dunning Jr.; W.J. Hunt; W.A. Goddard III 📂 Article 📅 1969 🏛 Elsevier Science 🌐 English ⚖ 452 KB

It is shown that the excited singlet ($8 o --) state (v) of planar ethylene in both the Llarkee-Fdck zn& z-electron configuration interaction descriptions is quite diffuse. The extent of the F-orbital in the ii-direction as measured by (22) is 42 a$ in the V state as compared to 2.7 a; in the corres

On some properties of the lowest nπ* and
✍ C. Mijoule; P. Yvan 📂 Article 📅 1976 🏛 Elsevier Science 🌐 English ⚖ 391 KB

Scmi-cmpnlck~l calculations dre rcportcd for the lowest nn\* and BIT\* clcctromc triplet statcs of berwaldchydc. IIqulhbrmm gcomctrws, spin drpole-dlpolc and spin-orbIt contributions to the 2I.S paramcterr; ns well .IS oscillator strcngthP 1) + SO arc presented and discussed for both states.

Electron impact excitation of the single
✍ D.E. Love; K.D. Jordan 📂 Article 📅 1995 🏛 Elsevier Science 🌐 English ⚖ 388 KB

The electron impact excitation functions of the 1 3Blu and l l Blu ~r -\* 'Jr" states of ethylene are measured. The triplet excitation function has a broad peak near 6.5 eV that is attributed to the 'rr-I('rr ~ )2 anion state, and the singlet excitation function displays sharp structure near thresho

Multiconfiguration wavefuntions for the
✍ Charles F. Bender; Thom.H. Dunning Jr.; Henry F. Schaefer III; William A. Goddar 📂 Article 📅 1972 🏛 Elsevier Science 🌐 English ⚖ 848 KB

Ab initio calculations have been carried out for the T(3B,u) and V('BIu) states of ethylene in a planar nuclear conf@ration. A "double-zeta" gaussian basis, augmented by diffuse functions, was used. A wide variety of configuration interaction wavefunctions (including as many as 1605 configurations)