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??-Push-pull substitution in iminophosphanes, a theoretical study

✍ Scribed by Schoeller, Wolfgang W. ;Busch, Thilo ;Niecke, E.

Publisher
Wiley (John Wiley & Sons)
Year
1990
Tongue
English
Weight
181 KB
Volume
123
Category
Article
ISSN
0009-2940

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πŸ“œ SIMILAR VOLUMES

Iminophosphanes as pseudocarbenes: A the
Iminophosphanes as pseudocarbenes: A theoretical study of product formation
✍ Wolfgang W. Schoeller; Thilo Busch; JΓΌrgen Niemann; Thomas Dabisch; W.-D. Stohre πŸ“‚ Article πŸ“… 1991 πŸ› John Wiley and Sons 🌐 English βš– 409 KB

## P(III) double bond systems possess two closely spaced frontier orbitals, a rr-orbital and a a-orbital. I n the parent iminophosphane the orbital sequence is a (HOMO) and n* (LUMO). Thus, it is isolobal to a singlet carbene and undergoes self-dimerization via a [2 + 1 ] cycloaddition. The result