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Purines. IX. Reaction of 9-Phenyl-9H-purine-2-carbonitriles with Grignard Reagents

โœ Scribed by Tanji, Ken-ichi; Higashino, Takeo

Book ID
111929338
Publisher
Japan Institute of Heterocyclic Chemistry
Year
1990
Tongue
English
Weight
142 KB
Volume
30
Category
Article
ISSN
0385-5414

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a b s t r a c t Lithiation of 6-chloro-9-(tetrahydro-2H-pyran-2-yl)-9H-purine with LiTMP, gave access to 6-chloro-2,8dihalogenated purine derivatives. In particular, the 6-chloro-2,8-diiodopurine derivative is an interesting new intermediate which gave regioselectively various 2-alkynylated compound