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Purine N-oxides: XXXVII. Derivatives from 6-chloropurine 3-oxide

โœ Scribed by Alfredo Giner-Sorolla


Book ID
112122470
Publisher
Journal of Heterocyclic Chemistry
Year
1971
Tongue
English
Weight
345 KB
Volume
8
Category
Article
ISSN
0022-152X

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Products derived from oxidations of 3,4-
โœ Louis D. Quin; Xiao-Ping Wu ๐Ÿ“‚ Article ๐Ÿ“… 1991 ๐Ÿ› John Wiley and Sons ๐ŸŒ English โš– 704 KB

Oxidation of' 3,4-dimethyl-l-phenylphosphole with peracids or peroxides gives a relatively stable P-oxide, which can be used in Diels-Alder reactions to give derivatives with the 7-phosphanorbornene framework. Oxygen insertion into a C-P bond of this framework occurs smoothly with m-chloroperbenzoic