𝔖 Bobbio Scriptorium
✦   LIBER   ✦

Pure rotational Raman spectra of hydrazoic acid HN3 and DN3

✍ Scribed by Jørgen Bendtsen

Publisher
John Wiley and Sons
Year
1977
Tongue
English
Weight
632 KB
Volume
6
Category
Article
ISSN
0377-0486

No coin nor oath required. For personal study only.

✦ Synopsis

The pure rotational Raman spectra of HN3 and DN3 have been photographed in the spectral range -100 Cm' to 470 cn-'. The ve intense AK = 0 transitions, ORK(J) and OSK(J), and the weak asymmetry-allowed AK = 1 and 2 transitions, QK, "QK, "SK (J) and "SK (J), were observed and measured. The analyses of the spectra with AK # 0 primarily yield information on the K-dependent parameters of the molecules. For HN3 the following constants have been determined: A = 20.3815(25) cm-'; DK = 8.706(92) X lo-' cm-'; H K = 7.38(93) x cm-'. For DN, the results are A = 11.4916(24) cm-'; DK = 2.931(36) X lo-' an-'; HK = 2.00(32) x cm-'.

📜 SIMILAR VOLUMES

Analyses of the High-Resolution Infrared
Analyses of the High-Resolution Infrared Absorption Spectra of the ν2and ν3Bands of Deuterated Hydrazoic Acid (DN3)
✍ Camilla Skytte Hansen; Jørgen Bendtsen; Flemming M. Nicolaisen 📂 Article 📅 1996 🏛 Elsevier Science 🌐 English ⚖ 233 KB

The infrared absorption spectra of the wavenumber regions including the n 3 and n 2 fundamental bands of DN 3 have been recorded with a spectral resolution of 0.003 cm 01 . In the region between 1105 and 1311 cm 01 the transitions observed are due to n 3 and the overtone band 2n 6 and in the region