Pulsed laser pyrolysis of dimethylnitramine and dimethylnitrosamine
โ Scribed by Donald F. McMillen; S.Esther Nigenda; Alicia C. Gonzalez; David M. Golden
- Book ID
- 118412781
- Publisher
- Elsevier Science
- Year
- 1987
- Tongue
- English
- Weight
- 204 KB
- Volume
- 43
- Category
- Article
- ISSN
- 1386-1425
No coin nor oath required. For personal study only.
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The short-lived molecule chloroketene (ClHCCO) was generated by the pyrolysis of chloroacetyl chloride in a hightemperature nozzle and the infrared laser-absorption spectrum of its 2 fundamental band was measured between 2153 and 2161 cm ฯช1 . The spectrum was greatly simplified by comparison with a
Pulsed laser powered homogeneous pyrolysis ( LPHP) is a technique which can be used to measure rate parameters for purely homogeneous unimolecular decomposition reactions at high temperatures (600-1500 K). The reaction temperature in pulsed LPHP may be obtained from the speed of sound in the reactin