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Pulsed-laser photochemical study of tris(2,2'-bipyridine)chromium(III) ion in acidic and alkaline aqueous media

✍ Scribed by Lilie, Jochen; Waltz, William L.

Book ID
127084510
Publisher
American Chemical Society
Year
1983
Tongue
English
Weight
800 KB
Volume
22
Category
Article
ISSN
0020-1669

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## Abstract The kinetics of a net two‐electron transfer between an authentic Mn^IV^ complex, [Mn(bigH)~3~]^4+^ (__Fig.β€…1__; bigH = biguanide = C~2~N~5~H~7~), and nitrite in aqueous solution in the pH interval 2.00–3.60 is described. Stoichiometric data for the reaction clearly indicates Ξ”[Mn^IV^]/Ξ”