Pulsed EPR Study of Manganese g = 4.1 Signal in Plant Photosystem II
✍ Scribed by A.V. Astashkin; Y. Kodera; A. Kawamori
- Publisher
- Elsevier Science
- Year
- 1994
- Tongue
- English
- Weight
- 624 KB
- Volume
- 105
- Category
- Article
- ISSN
- 1064-1866
No coin nor oath required. For personal study only.
✦ Synopsis
A light-induced (g=4.1) EPR signal of the manganese cluster in the oxygen-evolving complex of plant photosystem II was investigated by an electron-spin-echo method. The dependence of the ESE signal amplitude on the intensity of the microwave magnetic field (H_{1}) was consistent with the model assuming a manganese electron spin of (\frac{5}{2}) with EPR spectrum characteristics determined by nearly rhombic symmetry of the crystalline field. c. 1994 Academic Press, Inc.
📜 SIMILAR VOLUMES
## Abstract The ligand (N^1^‐[3‐(2‐aminoethylimino)‐1,1‐dimethylbutyl]ethane‐1,2‐diamine), L^1^, induces a high ligand field on the central Ni^II^ ion. Thus it is relatively easy to oxidize(Ni^II^L^1^)^2+^. However, the kinetic stability of the Ni^III^L^1^ complexes is considerably lower than that