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Pulse radiolysis studies of alkaline iron(III) and iron(VI) solutions. Observation of transient iron complexes with intermediate oxidation states

✍ Scribed by Rush, James D.; Bielski, Benon H. J.


Book ID
127293947
Publisher
American Chemical Society
Year
1986
Tongue
English
Weight
455 KB
Volume
108
Category
Article
ISSN
0002-7863

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## Abstract The kinetics of formation of the [PVA. Mn^VI^O] intermediate complex have been measured by the conventional spectrophotometric technique. The rate of formation of the complex was found to be given by the expression d[Complex]/d__t__ = __k__~1~[MnO‐~4~][PVA^βˆ’^]. The results showed that t