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Pulse Radiolysis of Supercritical Water. 2. Reaction of Nitrobenzene with Hydrated Electrons and Hydroxyl Radicals †

✍ Scribed by Marin, Timothy W.; Cline, Jason A.; Takahashi, Kenji; Bartels, David M.; Jonah, Charles D.

Book ID
126004730
Publisher
American Chemical Society
Year
2002
Tongue
English
Weight
281 KB
Volume
106
Category
Article
ISSN
1089-5639

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## Abstract The hydrated electron (e^−^~aq~) and hydroxyl radical rate constants with 18 acrylate‐, methacrylate‐, crotonate‐, fumarate‐ and maleate esters are discussed. The constants approach the diffusion‐controlled limit. __k__(e^−^~aq~) and __k__(OH) change in opposite direction; if __k__(e^−^