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Pulse polarography: V. Kinetics of pyruvic and glyoxylic acid reactions

✍ Scribed by A.W. Fonds; J.L. Molenaar; J.M. Los

Publisher
Elsevier Science
Year
1969
Weight
761 KB
Volume
22
Category
Article
ISSN
0022-0728

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In aqueous media (pH 2.5 -6.0), the Mn IV tetramer [Mn 4 (m-O) 6 A C H T U N G T R E N N U N G (bipy) 6 ] 4+ (1 4+ ; bipy = 2,2'-bipyridine) oxidizes both glyoxylic and pyruvic acid to formic and acetic acid, respectively, under formation of CO 2 . Kinetics studies suggest that the species 1 4+ , it