Pulse photolysis rate constants of the decay of ester peroxide radicals
โ Scribed by Nikolaev, A. I. ;Martemianov, V. S. ;Safiullin, R. L. ;Ibragimova, L. G.
- Book ID
- 112685954
- Publisher
- Springer
- Year
- 1984
- Tongue
- English
- Weight
- 214 KB
- Volume
- 24
- Category
- Article
- ISSN
- 0133-1736
No coin nor oath required. For personal study only.
๐ SIMILAR VOLUMES
## Abstract Propagation rate constants for the free radical polymerization of methacrylonitrile (MAN) have been obtained by pulsed laser photolysis (PLP). The temperature dependence of the propagation rate constants indicates a frequency factor of 10^(6,43 ยฑ 0,26)^ L ยท mol^โ1^ ยท s^โ1^ and an activa
The rotating-sector method has been applied to the photoinitiated radical-chain decomposition of formamide at 300ยฐC to measure the rate constant for the bimolecular disappearance of NH2 radicals. The decomposition is propagated by the reactions Conditions were chosen so that reaction (1) was rate c