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Pull-push mechanism for the 1,2-hydrogen rearrangement of carbenes. Substituent and deuterium isotope effects for thermal decomposition of 1-phenyl-2-diazopropanes

โœ Scribed by Su, Dean T. T.; Thornton, Edward R.


Book ID
126970332
Publisher
American Chemical Society
Year
1978
Tongue
English
Weight
552 KB
Volume
100
Category
Article
ISSN
0002-7863

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A very high S-deuterium kinetic isotope effect, k(CH3)/k(CD3) =2.l3 at ~o'c, was found for the solvolysis of 2-(3'-chlorophenyl)-l,l,l-trifluoro-2propyl tosylate(&) and the a-CD3 analogue