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Pt[In–C(SiMe3)3]4 – eine zu Pt(CO)4 analoge Verbindung mit einem durch vier InR-Liganden ideal tetraedrisch koordinierten Platinatom

✍ Scribed by Werner Uhl; Sandra Melle


Publisher
John Wiley and Sons
Year
2000
Tongue
German
Weight
81 KB
Volume
626
Category
Article
ISSN
0372-7874

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✦ Synopsis


Pt[In±C(SiMe 3 ) 3 ] 4 ± a Pt(CO) 4 Analogous Compound with a Platinum Atom Tetrahedrally coordinated by Four InR Ligands Abstract. The reaction of the tetrahedral alkylindium(I) compound In 4 [C(SiMe 3 ) 3 ] 4 (1) with bis(cyclooctadiene)platinum(0) afforded the compound Pt[InC(SiMe 3 ) 3 ] 4 (2), which is an analogue of the thermally unstable carbonyl complex Pt(CO) 4 and possesses a platinum atom tetrahedrally coordinated by four InR ligands.