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Pteridines. 51. A new and unequivocal route to C-6 carbon-substituted pterins and pteridines

โœ Scribed by Taylor, Edward C.; Ray, Partha S.


Book ID
126264845
Publisher
American Chemical Society
Year
1987
Tongue
English
Weight
590 KB
Volume
52
Category
Article
ISSN
0022-3263

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## Abstract Pteridines substituted with a 1,1โ€, 1,2โ€, or 1,1,3โ€substituted alkenyl group (mostly (__E__)โ€configured) at C(6) were synthesized in high yields by the intramolecular nitrosoโ€ene reaction of 4โ€(alkenoylamino)โ€2โ€aminoโ€6โ€benzyloxyโ€5โ€nitrosoโ€ and 4โ€(alkenoylamino)โ€2,6โ€diaminoโ€5โ€nitrosopyri