Pt-doped and SnO2-templated TiO2: properties and reactivity towards CO
β Scribed by P.A. Sermon; T.J. Walton
- Publisher
- Elsevier Science
- Year
- 1997
- Tongue
- English
- Weight
- 369 KB
- Volume
- 101-103
- Category
- Article
- ISSN
- 0167-2738
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β¦ Synopsis
Pt-doped and SnO,-ternplated TiO, can be prepared by sol-gel methods and are very active in CO oxidation especially at low PC0 and high 0,:CO ratios. It may also have activity in CO oxidation promoted by water vapour at moderate temperatures of reaction. Scanning calorimetry and residual gas analysis suggest that 0 finds it relatively difficult to establish itself on a surface precovered with CO and it may be that water-generated OH groups at the F't-oxide interface accelerate this particular process.
π SIMILAR VOLUMES
Electronic conductivity, mixed conductivity and Schottky-barrier sensors based upon the oxides SnOz and TiOz which are modified or contacted by the metals Pd and Pt can be used to detect gases like CO, CH4, H2 and 0,. The response signals of these different types of sensors result from changes in su
Thermal desorption of D, from oudized titanium surfaces, covered wnh various amounts of platurum, shows no detectable irreversible adsorpuon for up to three monolayers of Pt when the substrate tcmpersture is 130 K. Twelve monolayers of Pt gtve a substrate that adsorbs signdkant amounts of both CO 3n