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Pseudohalogenation of methyl 9-hydroxy-cis-12-and 12-hydroxy-cis-9-octadecenoate

โœ Scribed by Fehmida Naqvi; Abdul Rauf; M. M. Siddiqui; M. S. Ahmad; S. M. Osman


Book ID
107495134
Publisher
Springer-Verlag
Year
1997
Tongue
English
Weight
470 KB
Volume
74
Category
Article
ISSN
0003-021X

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Preparation of methyl cis-9,cis-12-octad
โœ R.O. Adlof; E.A. Emken ๐Ÿ“‚ Article ๐Ÿ“… 1981 ๐Ÿ› Elsevier Science ๐ŸŒ English โš– 357 KB

An eight-step synthesis is described which gives an overall yield of ~30% methyl cis-9,cis-12-octadecadienoate-16,16,17,17-d 4. The preparation utilizes easily obtainable starting materials. Tris(triphenylphosphine)chlororhodium (I) catalyst is used for incorporation of the deuterium isotopes. The d