Pseudohalogen derivatives of bis(cyclopentadienyl)titaniumIII
✍ Scribed by R. Coutts; P.C. Wailes
- Publisher
- Elsevier Science
- Year
- 1967
- Weight
- 164 KB
- Volume
- 3
- Category
- Article
- ISSN
- 0020-1650
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The bis-cyclopentadienyl hydride chemistry of the elements niobium and tantalum has been dominated by the family of trihydride complexes, namely Cp 2 MH 3 (M= Nb, Ta, Cp = C 5 H 5 , C 5 Me 5 , C 5 H 4 SiMe 3 , C 5 H 3 (SiMe 3 ) 2 and related substituted cyclopentadienyl rings). The chemical and spec
The title compound, 1,2-bis(4-nitrophenyl)ferrocene, [Fe(C 5 H 5 )(C 17 H 11 N 2 O 4 )], crystallizes with the planes of the two vicinal 4-nitrophenyl rings subtending angles of 46.04 (6) and 36.30 (7) at the plane of the substituted cyclopentadiene ring of the ferrocene moiety.
Single-crystal X-ray study T = 137 K Mean '(C±C) = 0.005 A Ê R factor = 0.048 wR factor = 0.134 Data-to-parameter ratio = 18.9 For details of how these key indicators were automatically derived from the article, see http://journals.iucr.org/e.