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Pseudodimorphism of the Trans-9,10-dihydro-9,10-ethanoanthracene-11,12-dicarboxylic Acid Clathrates with Acetic and Propionic Acids

โœ Scribed by L.Yu. Izotova; B.T. Ibragimov; E. Weber; D.M. Ashurov; S.A. Talipov; M. Perrin

Book ID
111589617
Publisher
Springer Netherlands
Year
2004
Tongue
English
Weight
129 KB
Volume
48
Category
Article
ISSN
0923-0750

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Asymmetric cycloaddition routes to both
Asymmetric cycloaddition routes to both enantiomers of trans-9,10-dihydro-9,10-ethanoanthracene-11,12-dicarboxylic acid
โœ Linda Thunberg; Stig Allenmark ๐Ÿ“‚ Article ๐Ÿ“… 2003 ๐Ÿ› Elsevier Science ๐ŸŒ English โš– 259 KB

Fumarates prepared from a series of optically active alcohols were used as dienophiles in Lewis acid catalyzed asymmetric cycloadditions to anthracene. The reactions gave high yields and d.e.'s of the diester cycloaddition products and acid hydrolysis could be performed under conditions yielding onl