Pseudocapacitors: Fundamentals to High Performance Energy Storage Devices (Engineering Materials)

✍ Scribed by Ram K. Gupta (editor)

• Publisher: Springer
• Year: 2023
• Tongue: English
• Leaves: 403
• Category: Library

✦ Synopsis

This book provides an overview of pseudocapacitive materials, including their fundamentals, synthetic methods, architectural enhancements to boost their properties, and emerging materials. It covers numerous strategies to enhance their performance, such as altering morphology, doping, introducing multivalent ions, designing devices, and utilizing emerging pseudocapacitive materials. The book also delves into fundamental approaches for fine-tuning the properties of pseudocapacitive materials and explores their applications in energy storage devices, with a specific focus on emerging pseudocapacitive materials and their utilization in energy storage devices.

✦ Table of Contents

Preface
Contents
Pseudocapacitance: An Introduction
1 Introduction
2 Classification
2.1 Electric Double-Layer Capacitors (EDLCs)
2.2 Pseudocapacitors (PC)
2.3 Hybrid Supercapacitor
3 Conclusion
References
Pseudocapacitance: Fundamentals to Advanced Applications
1 Introduction
2 Background
3 Types of Energy Storage Devices
4 Role of Pseudocapacitive Materials
5 Types of Pseudocapacitive Mechanisms
6 Electrochemical Features of Pseudocapacitance
7 Pseudocapacitive Electrode Architectures
8 Various Materials of Energy Storage Devices
8.1 Aqueous Pseudocapacitor Materials
8.2 Emergence of Pseudocapacitance in RuO2
8.3 Non-aqueous Electrolyte Pseudo Capacitor Materials
9 Conclusions
References
Pseudocapacitance: Mechanism and Characteristics
1 Introduction
2 Capacitance and Pseudocapacitance in the Electrode–Electrolyte Interface
3 Pseudocapacitance Charge Transfer Mechanisms
3.1 Under-Potential Deposition
3.2 Surface Redox Pseudocapacitance
3.3 Intercalation Pseudocapacitance
4 Origin of Pseudocapacitance
5 Intrinsic and Extrinsic Pseudocapacitance
6 Electrochemical Features of Pseudocapacitance
6.1 CV and GCD Characteristics
6.2 Electrochemical Impedance Spectroscopy Characteristics
7 Evaluation Parameters: Specific Capacitance and Specific Capacity
8 Understanding the Transition Region, Capacitive and Diffusive Contribution in Pseudocapacitors
9 Conclusion
References
Emerging Pseudocapaciting Materials
1 Introduction
2 Pseudocapaciting Materials Developed Based on the Glycerate Template Method
2.1 Glycerate Template Method
2.2 Emerging Progress with the Glycerate Template Approach
3 Composite Pseudocapaciting Materials Consisting of Nanosheets and/or Nanoplates
4 Negative Electrode Pseudocapaciting Materials
4.1 Metal Sulfides for Negative Electrode Pseudocapaciting Materials
4.2 Metal Nitrides for Negative Electrode Pseudocapaciting Materials
4.3 Hydroxide/LDH for Negative Electrode Pseudocapaciting Materials
4.4 Conducting Polymers, Metal Oxides, and MXenes for Negative Electrode Pseudocapaciting Materials
5 Other Emerging Pseudocapaciting Materials
6 Conclusion
References
Pseudocapacitance: Tuning Electrochemical Properties
1 Introduction
2 Tuning Strategies for Intrinsic Pseudocapacitive Materials
3 Tuning Strategies for Extrinsic Pseudocapacitive Materials
3.1 Nanostructuring
3.2 Defect Engineering
3.3 Interlayer Engineering
3.4 Heterostructure Engineering
4 Conclusion and Perspectives
References
Pseudocapacitive Materials for Electrolytes
1 Introduction to Pseudocapacitive Materials for Electrolytes
2 Types of Electrolytes for Energy Applications
2.1 Aqueous Electrolytes
2.2 Non-aqueous Electrolytes (Organic, Ceramic, and Ionic Liquid-Based)
2.3 Gel Polymer Electrolytes (GPEs)
2.4 Solid Polymer Electrolytes (SPEs)
3 Metal-Free Pseudocapacitive Materials for Electrolytes
3.1 Carbon-Derived Pseudocapacitive Materials
3.2 Conductive Polymers Pseudocapacitive Materials
4 Metal-Derived Pseudocapacitive Materials for Electrolytes
4.1 Metal Oxides (MOs) and Mixtures of Transition Metal Oxides (MTMOs)
4.2 Chalcogenides and MXenes Pseudocapacitive Materials
4.3 Metal–Organic Frameworks Pseudocapacitive Materials
5 Conclusions
6 Challenges and Future Directions in Pseudocapacitive Materials for Energy Applications
References
Electrochemical Properties of Metal Hydroxides
1 Introduction
2 Nickel Hydroxides
3 Manganese Hydroxides
4 Cobalt Hydroxides
5 Doped Metal Hydroxides
6 The Competition Between Morphology and Chemical Doping
7 Metal Hydroxide Composites
7.1 Bimetallic Hydroxide Composites
7.2 Ternary Metal Hydroxide Composites
8 Layered Double Hydroxides (LDHs)
8.1 Aluminum Based LDHs
8.2 Modification of LDHs
References
Pseudocapacitance in Double Perovskite Material
1 Introduction
1.1 Advances in Double Perovskite Materials
1.2 Synthesis Approaches of DPMs
2 Electrochemistry of DPMs
2.1 Charge Storage Mechanism
2.2 Electrochemical Stability and Reversibility
2.3 Electrochemical Kinetics
2.4 Cation Leaching Assessing
3 DPMs as Pseudocapacitive Electrodes
3.1 Double Perovskite Material as Electrode Materials
3.2 Challenges and Future Perspectives
4 Conclusions
References
Conducting Polymers for Pseudocapacitors
1 Introduction
2 Types of Pseudocapacitance
2.1 Adsorption Pseudocapacitance
2.2 Redox Pseudocapacitance
2.3 Intercalation Pseudocapactiance
2.4 Electrochemical Capacitors
3 Polymeric Materials
4 Polymeric Carbon-Based Materials
5 Polymeric Composite Materials
6 Conclusion and Future Perspective
References
MXenes for Pseudocapacitors
1 Introduction
2 Charge Storage and Kinematics in MXene
3 Pseudocapacitive Asymmetric Devices
4 Intercalated Pseudocapacitor
4.1 Aqueous System
4.2 Non-Aqueous System
5 Strategies to Tune the Interlayer Spacing
6 Interlayer Spacing of MXene in Pesudocapacitor
7 Composites and Hybrid Structures of MXene
8 Summery and Future Prospective
References
MXenes-Based Composites for Pseudocapacitors
1 Introduction
2 MXenes Based Composites for Pseudocapacitors
2.1 MXenes/Metal Compound Composites
2.2 MXenes/polymer Composites
2.3 MXenes Based Other Composites
3 Summary
References
Hydrogel and Its Composites for Pseudocapacitors
1 Introduction
2 Fundamentals of Pseudocapacitors
3 Hydrogel and Composites
4 Hydrogel and Composites for Pseudocapacitors
5 Conclusion
References
Pseudocapacitive Materials for 3D Printed Supercapacitors
1 Introduction
2 3D Printing Technologies
2.1 Fused Deposition Modeling
2.2 Stereolithography
2.3 Selective Laser Sintering
2.4 Digital Light Processing
2.5 Binder Jetting
2.6 Direct Ink Writing
2.7 Inkjet Printing
3 Electrode Design and Architectures
3.1 Interdigitated Structures
3.2 Vertically Aligned Structures
3.3 Complex 3D Structures
4 Pseudocapacitive Materials-Based 3D Printed Supercapacitors
4.1 Transition Metal Oxides
4.2 Conducting Polymers
4.3 Metal Dichalcogenides
4.4 Transition Metal Carbides/carbonitrides (MXenes)
4.5 Metal–organic Frameworks
4.6 Hybrid Electrode Combination
5 Implications and Future Perspectives
References
Pseudocapacitive Materials for Flexible Supercapacitors
1 Introduction
2 Pseudocapacitive Materials for FSCs
2.1 Metal Oxides and Their Composites for FSCs
2.2 Conducting Polymers and Their Composites for FSCs
2.3 Mxenes and Their Composites for FSCs
3 Device Configurations of Pseudocapacitive Material-Incorporated FSCs
3.1 One-Dimensional Fiber-Shaped FSCs
3.2 Two-Dimensional Film-Shaped FSCs
3.3 Three-Dimensional Structural FSCs
4 Practical Applications of Pseudocapacitive Material Incorporated FSCs
5 Summary and Outlooks
References
Redox-Active Polymers for Batteries
1 Introduction
2 Redox-Active Polymers
2.1 Classification of Redox-Active Polymers
3 Effects of Polymer Architecture on Cell Properties
4 Concepts of Electron Transfer in RAPs
5 Redox- Active Polymers for Batteries
5.1 Development of Polymer-Based Aqueous RFB
5.2 Development of Polymer-Based Nonaqueous RFB
5.3 Polymer Suspension-Based RFB
6 Conclusions
References
Carbon-Based Pseudocapacitive Materials for Next Generation Batteries
1 Introduction
2 Carbon-Based Materials
2.1 Carbon Nanotubes (CNTs)
2.2 Carbon Nanofibers (CNFs)
2.3 Graphene
2.4 Graphite
3 Metal-Based Materials
3.1 Metal Oxides
3.2 Metal Sulfides
4 Metal–Carbon Composites
4.1 Metal Oxide/Sulfide with CNT Composites
4.2 Metal Oxide/Sulfide with CNF Composites
4.3 Metal Oxide/Sulfide with Graphene/Graphite Composites
5 Conclusion and Perspective
References
Surfactant-Assisted Pseudocapacitive Materials for Li-Ion Batteries
1 Introduction
2 Properties and Advantages of Surfactants in Active Materials of LIBs
3 Synthesis Methods of Surfactant-Assisted Pseudocapacitive Materials
3.1 Solvothermal Methods
3.2 Hydrothermal Methods
3.3 Sol–gel Methods
3.4 Solid-State Methods
4 Structural Morphologies of Surfactant-Assisted Psedocapacitive Materials
4.1 Rod-Like Structures
4.2 Plate-Like Structures
4.3 Spherical-Like Structures
5 Conclusion
References
Pseudocapacitive Materials for Metal-Sulfur Batteries
1 Introduction
2 Metal-Sulfur Batteries
3 Pseudocapacitive Materials
3.1 Transition Metal Oxides/Hydroxides
3.2 Transition Metal Chalcogenides (TMCs)
3.3 Transition Metal Phosphides/Borides
3.4 Conducting Polymers
3.5 MXenes (Nitrides and Carbides)
3.6 MOF-Derived Materials
4 Conclusion and Future Perspective
References
Pseudocapacitive Materials for Metal-Air Batteries
1 Introduction
2 Metal-Air Batteries: Fundamentals and Working
3 MAB Using Pseudocapacitive Materials
3.1 Transition Metal Oxides/Sulfides/Phosphide
3.2 Conducting Polymers
3.3 Composites
4 Flexible Metal-Air Batteries
5 Conclusion and Future Remark
References
Pseudocapacitive Materials-Based Metal-Air Batteries
1 Introduction
2 Metal Air Battery Working Mechanism
3 Li-Air Batteries
4 Na-Air Batteries
5 Zn-Air Batteries
6 Alternative Metal Air Batteries
7 Summary and Vision
References
Pseudocapacitive Materials for 3D Printed Batteries
1 Introduction
2 Batteries: Fundamentals and Working
3 3D Printed Batteries Using Pseudocapacitive Materials
3.1 Transition Metal Oxides
3.2 Transition Metal Sulfides
3.3 Transition Metal Phosphide
3.4 Conducting Polymers
3.5 Composites Based on Pseudocapacitive Materials
4 Flexible 3D Printed Batteries Using Pseudocapacitive Materials
5 Conclusion and Future Remark
References