“Pseudo-cationic” trifluoromethylation of enol esters with sodium trifluoromethanesulfinate.

✍ Scribed by Bernard R. Langlois; Eliane Laurent; Nathalie Roidot

• Book ID: 104224672
• Publisher: Elsevier Science
• Year: 1992
• Tongue: French
• Weight: 283 KB
• Volume: 33
• Category: Article
• ISSN: 0040-4039
• DOI: 10.1016/s0040-4039(00)91604-6

✦ Synopsis

Enol esters are converted into corresponding trifluoromethylated keroncs and/or cnol esters with sodium trifluoromethanesul~nate and t-butyl hydroperoxide in the presence of catalytic amounts of CU(II).