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Proximity effects. XLV. Solvolyses of bicyclo[4.2.0]octyl derivatives

โœ Scribed by Cope, Arthur C.; Gleason, Robert W.; Moon, Sung; Park, Chung Ho

Book ID
127372407
Publisher
American Chemical Society
Year
1967
Tongue
English
Weight
677 KB
Volume
32
Category
Article
ISSN
0022-3263

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โœ Cyril A. Grob; Roland Rich ๐Ÿ“‚ Article ๐Ÿ“… 1979 ๐Ÿ› John Wiley and Sons ๐ŸŒ German โš– 415 KB ๐Ÿ‘ 1 views

Hydrolysisofbicyclo[2.2.2]octylp-nitrobenzenesulfonate (14a,X =p-N02C6H4S03), and nineteen 4-R-substituted derivatives 14b-14 t in 70% aqueous dioxane yield the corresponding bicyclo [2.2.2]octanols 14 (X = OH), exclusively. The 7-center fragmentation to 1,4-dimethylidene-cyclohexane (15) is not obs