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Proximity effect: the role of out-of-plane bending modes in radiationless transitions

✍ Scribed by W.A. Wassam Jr.; E.C. Lim

Publisher
Elsevier Science
Year
1977
Tongue
English
Weight
297 KB
Volume
52
Category
Article
ISSN
0009-2614

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✦ Synopsis

The qumturn statisticA approach ~CI rclamtion proccsscs is cmpluycd in an mvc+tigJtwn of tllc role of vlbronic inter-&ions in radiationless transitions. The results iudicatc that vtbronic.dly active out-of-phnc vibrations can be tilt domlnmt ncccptmji modes in motccuies ~111 clo%e-lying nn* and nn* statu.

Due to their large frequejl~ies~ the C-H stret~hirlg modes are believed to be the dominant accepting modes for IS,> + ISO) and IT1) + ISo) radiationless transitiws of nrormtic hydrocarbons*.

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