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Proximity effect in the oxidation of dithiols with 3-methyllumiflavin

✍ Scribed by Toshiyuki Nagata; Ken Fujimori; Shigeru Oae

Publisher
John Wiley and Sons
Year
1992
Tongue
English
Weight
474 KB
Volume
3
Category
Article
ISSN
1042-7163

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✦ Synopsis

Abstract

Rates of oxidation of various dithiols with 3‐methyllumiflavin to afford the corresponding cyclic disulfides have been examined at various pH values in 30% aqueous ethanol at 30°C. 1,3‐Propanedithiol, which affords 1,2‐dithiolane, has been found to be the most reactive among several dithiols tested in this oxidation. Kinetic results clearly show that highly strained 1,2‐dithiethanes are formed as primary products in the oxidation of vic‐dithiols with 3‐methyllumiflavin.

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