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Prototropism in (Pentamethylcyclopentadienyl)iridium Complexes with Pyrazole Ligands

✍ Scribed by Dr. Daniel Carmona; Prof. Dr. Luis A. Oro; Dr. M. Pilar Lamata; Prof. Dr. Josté Elguero; Dr. María del Carmen Apreda; Dr. Concepción Foces-Foces; Prof. Dr. Félix H. Cano


Publisher
John Wiley and Sons
Year
1986
Tongue
English
Weight
251 KB
Volume
25
Category
Article
ISSN
0044-8249

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## Abstract Iridium(III) complexes were designed and evaluated as efficient photoinitiators of polymerization reactions in combination with iodonium salts and silanes. Mechanistically, these reactions were shown to proceed through oxidative photoredox catalysis, generating aryl and silyl radicals u