✦ LIBER ✦

Protonation susceptibility of functional groups: A new parameter for interpreting chemical ionization mass spectra of bifunctional organic compounds

✍ Scribed by Hisao Nakata

Publisher: John Wiley and Sons
Year: 1992
Tongue: English
Weight: 277 KB
Volume: 27
Category: Article
ISSN: 1076-5174
DOI: 10.1002/oms.1210270607

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✦ Synopsis

A new parameter, the protonation susceptibility (PS), of functional groups in the cbemkal ionization mass spectrometry of bifunctional organic compounds k presented. In terms of quaskquilibrium tbeory of unimolecular decompositioa of the molecular protonated ion of [ MHI +, the relative PS corresponds to the relative area under P(E) curves of IMHI* ious that have a proton at different functional groups Numerical evaluation of tbe PS values of pertinent functiwpl groups was made by using particularly selected compounds The results clearly indicate that PS is hiependent of proton affinity (PA).

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