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Protonation of Excited State Pyrene-1-Carboxylate by Phosphate and Organic Acids in Aqueous Solution Studied by Fluorescence Spectroscopy

✍ Scribed by Zelent, Bogumil; Vanderkooi, Jane M.; Coleman, Ryan G.; Gryczynski, Ignacy; Gryczynski, Zygmunt


Book ID
119920491
Publisher
Biophysical Society
Year
2006
Tongue
English
Weight
409 KB
Volume
91
Category
Article
ISSN
0006-3495

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## Abstract During UV.‐irradiation of aliphatic carboxylic acids and esters in aqueous and nonaqueous solutions various alkyl and acyl type radicals derived from parent compounds and solvents have been observed by ESR.‐spectroscopy. The structures of the radicals point to α‐cleavage, β‐dehalogenati