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Protonation kinetics of anionic intermediates in the electrochemical reduction of triphenylethylene: a disproportionation mechanism

✍ Scribed by Farnia, Giuseppe; Maran, Flavio; Sandon�, Giancarlo; Severin, Maria Gabriella


Book ID
119951589
Publisher
Royal Society of Chemistry
Year
1982
Tongue
English
Weight
757 KB
Volume
9
Category
Article
ISSN
1472-779X

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The electrochemical reduction mechanism of pnitrobenzoie acid (NBA) in DMF has been investigated by cyclic voltammetry, poiarography and controlled potential macroscale elecWolysis. The stoiehiometry of the reaction occurring at the first cathodic wave involves 0.8 Faraday and yields 0.2 moles of ph