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Protonation and H 2 Heterolysis Reactions of Electrophilic (η 5 -C 5 R 5 )Ru(dfepe)(X) (R = H, Me; X = H, OTf) Complexes

✍ Scribed by Ontko, Allyn C.; Houlis, James F.; Schnabel, R. Chris; Roddick, Dean M.; Fong, Tina P.; Lough, Alan J.; Morris, Robert H.


Book ID
126150324
Publisher
American Chemical Society
Year
1998
Tongue
English
Weight
187 KB
Volume
17
Category
Article
ISSN
0276-7333

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Photochemical reactions of [(η5-C5R5)Mn(
✍ Bentley J. Palmer; Anna Becalska; Ross H. Hill 📂 Article 📅 1991 🏛 Elsevier Science 🌐 English ⚖ 646 KB

## The photolysis of [(T'-CsR,)Mn(CO),(NO)]' (RS=HZ, H4Me, MeS) was studied by Fourier transform IR spectroscopy in a low temperature 1,2-epoxyethylbenzene glass and in surface films. In each case the primary photoproduct was found to be [(~5-CsRS)Mn(CO)(NO)]'. The result of subsequent photoIysis