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Protonation and alkylation of organophosphorus compounds with trifluoromethanesulfonic acid derivatives

✍ Scribed by L. L. Tolstikova; A. V. Bel’skikh; B. A. Shainyan

Book ID
111460903
Publisher
Springer
Year
2011
Tongue
English
Weight
213 KB
Volume
81
Category
Article
ISSN
1070-3632

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Trifluoromethanesulfonic Acid Catalyzed
Trifluoromethanesulfonic Acid Catalyzed Alkylation of Arenes with Methyl (2R)-Glycidate
✍ Pablo J. Linares-Palomino; G. K. Surya Prakash; George A. Olah 📂 Article 📅 2005 🏛 John Wiley and Sons 🌐 German ⚖ 173 KB

## Abstract Methyl (__R__)‐glycidate (=methyl (__R__)‐oxiranecarboxylate; **2**) in superacidic trifluoromethanesulfonic acid medium reacts with electron‐rich arenes to give __α__‐hydroxy‐__β__‐arylpropanoate derivatives **3a**–**3f** with high stereospecificity. At the same time, the observed high