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Protonation and acetylation of tricarbonyl-5-exo-(isopropenyl)cyclohexa-1,3-dieneiron. Regiospecific formation of tricarbonyl-1-(substituted)cyclohexadienyliumiron cations

✍ Scribed by Brian F.G. Johnson; Jack Lewis; G.Richard Stephenson

Book ID: 104225990
Publisher: Elsevier Science
Year: 1980
Tongue: French
Weight: 137 KB
Volume: 21
Category: Article
ISSN: 0040-4039
DOI: 10.1016/s0040-4039(00)93666-9

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Replacement of SO2Ar in tricarbonyl-5α-(arylsulphonyl)cyclohexa-1,3-dieneiron complexes: regio- and stereocontrol in reactions of dienyliron cations with some nucleophiles

✍ L.F. Kelly; A.J. Birch 📂 Article 📅 1984 🏛 Elsevier Science 🌐 French ⚖ 201 KB

Regio-and enantiocontrolled bond formation in tricarbonylcyclohexadieneiron complexes is available via the reaction of their derived cations with sodium p-tolylsulphinate followed by nucleophilrdisplacement of S02Ar.