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Protonated forms of N-vinylpyrroles

โœ Scribed by M. V. Sigalov; E. Yu. Shmidt; B. A. Trofimov

Publisher
Springer US
Year
1988
Tongue
English
Weight
344 KB
Volume
24
Category
Article
ISSN
0009-3122

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Secondary phosphines 1-3 react readily with N-vinylpyrroles 4 and 5 under radical initiation to give regiospecifically anti-Markovnikov adducts, diorganyl-2-(1-pyrrolyl)ethylphosphines 6a-d, highly reactive building blocks for organic synthesis, in 88-91% yields.