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Proton tunneling in tropolone—Rg (Rg  Ar, Kr, Xe) van der Waals complexes

✍ Scribed by Hiroshi Sekiya; Taiji Nakajima; Hiroki Ujita; Takeshi Tsuji; Sayaka Ito; Yukio Nishimura

Publisher: Elsevier Science
Year: 1993
Tongue: English
Weight: 572 KB
Volume: 215
Category: Article
ISSN: 0009-2614
DOI: 10.1016/0009-2614(93)85709-w

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✦ Synopsis

The fluorescence excitation spectra of jet-cooled tropolone-Rg,(Rg=Ar, Kr, Xe) van der Waals r.omplexes in the A *B2-g 'A, region have been measured to investigate proton tunneling in the excited state of the complexes. We found that the intermolecular vibrations in the A 'B1 states of tropolone(OD)-Kr, and tropolone(OD)-Xe, couple with the proton motion.

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