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Proton tunneling in symmetric H-bond. A simple microscopic model

โœ Scribed by David Vitali


Publisher
Elsevier Science
Year
1995
Tongue
English
Weight
531 KB
Volume
192
Category
Article
ISSN
0301-0104

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Hydrogen-bonded pairs of the 2-methylimidazolium cation and 2-methylimidazole are expected to have matched pK a values, owing to chemical symmetry. These structures serve as models for enzyme active sites. Several crystalline salts of this system were prepared and characterized by crystallography an