In~mol~~ 2pn\* + 3dn charge transfer in the excited state of phenyl~e occurs very rapidly (<IO ps) both in ?&Fat 293 K and in EPA glass at 77 K. At room temperature a Iong;lived 425 nm transient (which is assgned to a reananged intermediate) is produced with a nse time of 30 ps, showing that the tra
โฆ LIBER โฆ
Proton transfer reactions in the excited state of 1-aminopyrene by picosecond/streak camera and nanosecond spectroscopy
โ Scribed by Haruo Shizuka; Kinzo Tsutsumi; Hiroshi Takeuchi; Ikuzo Tanaka
- Publisher
- Elsevier Science
- Year
- 1981
- Tongue
- English
- Weight
- 528 KB
- Volume
- 59
- Category
- Article
- ISSN
- 0301-0104
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Picosecond and nanosecond dynamics of the ion pair produced by the electron transfer reaction between the triplet state benzophenone ('BP\*) and 1,4-diazabicyclo[ 2.2.2loctane (DABCO) wasinvestigated by means oftransientabsorption spectroscopy and laser-induced photoconductivity measurement. It has