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Proton Transfer in Solid State: Mechanochemical Reactions of Imidazole with Metallic Oxides

✍ Scribed by José Fernández-Bertrán; Lila Castellanos-Serra; H. Yee-Madeira; Edilso Reguera

Publisher
Elsevier Science
Year
1999
Tongue
English
Weight
113 KB
Volume
147
Category
Article
ISSN
0022-4596

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✦ Synopsis

Mechanochemical reactions of crystalline imidazole with 23 metallic oxides have been studied by milling in a mortar and in ball mill vibrators of low and high mechanical intensity. The reactions were monitored by Fourier transform infrared spectroscopy (FTIR) and X-ray di4raction (XRD) techniques. ZnO, HgO, Ag 2 O, and Cu 2 O react rather readily in the mortar, forming the corresponding imidazolates but CdO, Ga 2 O 3 , and In 2 O 3 require intense mechanical milling to transform. CuO and NiO do not react immediately but turn bluish after a few months of aging. The oxides of Mg(II), Ca(II), Be(II), Al(III), Fe(II), Co(II), Co(III), Pb(II), Eu(III), Ce(III), Bi(III), Ti(IV), Zr(IV), and Sn(IV) are inert to imidazole even on strong milling for several hours.

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