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Proton transfer between carbon acids and methoxide: Studies in methanol, the gas phase and by ab initio MO calculations

โœ Scribed by Heinz F. Koch; Masaaki Mishima; Han Zuilhof


Book ID
112008866
Publisher
Wiley (John Wiley & Sons)
Year
1998
Tongue
English
Weight
686 KB
Volume
102
Category
Article
ISSN
0372-8323

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Ab initio molecular orbital calculations at the MP2/6-31G\*//MP2/6-31G\* + ZPE level have been performed in order to explore the reaction between CH 3 OH 2 + and CH 3 OH. The detailed mechanism of proton transfer, CH 3 OH 2 + + CH 3 OH ยฎ CH 3 OH + CH 3 OH 2 + , and of cationic nucleophilic substitut