Proton translocation in the singlet excited state of 4-methyl-2,6-diformyl phenol (MFOH) results in an interesting fluorescence band at 535 nm. The fluorescence emission and excitation spectra of MFOH are recorded and a time-correlated single-photon counting technique is used to determine the fluore
Proton transfer and anion formation in the ground and excited states of 4-methyl-2,6-diformyl phenol in highly polar aprotic solvents
✍ Scribed by R. Das; S. Mitra; S. Mukherjee
- Publisher
- Elsevier Science
- Year
- 1993
- Tongue
- English
- Weight
- 702 KB
- Volume
- 76
- Category
- Article
- ISSN
- 1010-6030
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Proton transfer in the ground and excited states of 4-methyl-2,6-diformylphenol (MFOH) in ethanol/water, ethanol/metha-no1 and ethanol/dioxane solvent mixtures has been studied using steady state and nanosecond transient emission spectroscopy. The lifetime is not affected much in water/alcohol mixtu
Excited-state proton transfer in 2-(2'-hydroxyphenyl)benzothiaxole (HBT) dissolved in pyridine is investigated. New absorptions and fluorescence bands are detected after addition of water or NaOH to the solution. The spectra are identical to the HBT anion absorption and fluorescence. Picosecond spec
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