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Proton polarizability of intramolecular hydrogen bonds with molecules non-conjugated and conjugated between donor and acceptor groups

✍ Scribed by Bogumił Brzeziński; Georg Zundel


Publisher
Elsevier Science
Year
1980
Tongue
English
Weight
404 KB
Volume
75
Category
Article
ISSN
0009-2614

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✦ Synopsis


Receveld 7 July 19e0, m fiial form 6 August 1980 Compounds wth mtramolecular hydrogen bonds are mvestlgated. When the hydrogen-bond donor and acceptor groups are not electromcally conjugated, IR contmua mdlcate a large proton polanzabibty. When they are ConJugated the contmua are very weak. Thus not only the proton potentd but also the dependence of the dipole moment on the vlbratlonal coordmate IS decwve for occurrence of the continua