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Proton nuclear magnetic resonance spectroscopy of aqueous solutions: complete elimination of the water resonance by spin-spin relaxation

✍ Scribed by Rabenstein, Dallas L.; Fan, Shiyan.

Book ID
115540634
Publisher
American Chemical Society
Year
1986
Tongue
English
Weight
740 KB
Volume
58
Category
Article
ISSN
0003-2700

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✍ Christopher T. G. Knight; Robin K. Harris πŸ“‚ Article πŸ“… 1986 πŸ› John Wiley and Sons 🌐 English βš– 421 KB

The 29Si spin-lattice relaxation times, &(%), of the various silicate anions present in high-purity alkaline silicate solutions are reported. Regular silicate cages display the longest T,(29Si) values and, in the case of the cubic octamenc cage, an unexpectedly large nuclear Overhauser enhancement,