Proton NMR study of the conformation of ring D and its side chains in chlorophyll derivatives
โ Scribed by Kevin M. Smith; Dane A. Goff; Raymond J. Abraham
- Publisher
- Elsevier Science
- Year
- 1981
- Tongue
- French
- Weight
- 227 KB
- Volume
- 22
- Category
- Article
- ISSN
- 0040-4039
No coin nor oath required. For personal study only.
โฆ Synopsis
The complex multiplet proton NMR pattern at 360 MHz of the propionic side chains in methyl pheophorbides and a pheofarnesin derived from bacteriochZorophyZl-d is capletely analyzed; the major preferred orientation in solution is found to be different from that determined by single crystal X-ray studies.
๐ SIMILAR VOLUMES
## Abstract Conformation of __N__โacetylโ(__E__)โdehydrophenylalanine __N__โฒ, __N__โฒโdimethylamide (Acโ(__E__)โฮPheโNMe~2~) in solution, a member of (__E__)โฮฑ, ฮฒโdehydroamino acids, was studied by NMR and infrared spectroscopy and the results were compared with those obtained for (__Z__) isomer. To