Determination of ligand lifetimes in the
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Tomas Larsson; Jozef Kowalewski
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Article
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1988
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John Wiley and Sons
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English
⚖ 239 KB
👁 1 views
The activation enthalpy and entropy for ligand exchange in the weak complex Ni(glycerol)i+ were estimated by variable-temperature proton spin-lattice relaxation time measurements at 9.4 and 6.3 T on a 0.044 molal solution of NiCI, in glyceroL A description of the dynamic process in terms of a simple